 
 
 
 
 
 
 
  
Consider a process whose outcome is uncertain. For example, we
throw a dice. The value the dice returns can have 6 values,
|  | (19.1) | 
 when you throw the dice?'' This probability can be
calculated using,
 when you throw the dice?'' This probability can be
calculated using,
|  | (19.2) | 
For a fair dice 
 for all the six possible
outcomes as shown in Figure 19.1.
 for all the six possible
outcomes as shown in Figure 19.1.
What is the expected outcome when we throw the dice? We next
calculate the expectation value which again is an integral,
 and
 and  . We have
. We have
 , the rest are all
zero as shown in Figure 19.2.
 , the rest are all
zero as shown in Figure 19.2.
Calculating the expectation value for the biased dice we have
|  | (19.4) | 
The expectation value is unchanged even  though the probability
distributions are different. Whether we throw the unbiased  dice
or the biased dice, the expected value is the same. Each time we
throw the dice, we will get a different value . In both cases the
values will be spread around 3.5 . The values will have a larger
spread for the fair dice as compared to the biased one. How to
characterize this? The root mean square or standard deviation
 tells this. The variance
 tells this. The variance  is calculated as,
 is calculated as,
|  | (19.5) | 
 the more is the spread. Let us
calculate the variance  for the fair dice,
 the more is the spread. Let us
calculate the variance  for the fair dice,
| ![\begin{displaymath}
\sigma^2=\frac{1}{6} \left[ (1-3.5)^2+(2-3.5)^2+ ... + (6-3.5)^2
\right],
\end{displaymath}](img1501.png) | (19.6) | 
 . For the biased dice
we have
. For the biased dice
we have
| ![\begin{displaymath}
\sigma^2=\frac{1}{2} \left[ (3-3.5)^2+(4-3.5)^2
\right],
\end{displaymath}](img1503.png) | (19.7) | 
 . We see that
 the fair dice has a larger variance and standard deviation then the
 unbiased one.  The uncertainty in the outcome is larger for the fair
 dice and is smaller for the biased one.
. We see that
 the fair dice has a larger variance and standard deviation then the
 unbiased one.  The uncertainty in the outcome is larger for the fair
 dice and is smaller for the biased one.
We now shift over attention to continuous variables. For example, x is
a random variable which can have any value between  and
 and  (Figure 19.3). What is
the probability that x has a value
(Figure 19.3). What is
the probability that x has a value  ?
 ?
This probability  is zero. We see this as follows. The probability
of any value between 0 and 10 is the same. There are infinite
points between  and
 and  and the probability of getting exactly
 and the probability of getting exactly
 is,
 is,
|  | (19.8) | 
The denominator is infinitely
large and the probability is thus zero. A correct question would
be, what is the probability that  has a value between
 and
 has a value between
 and  .  We can calculate this as,
.  We can calculate this as,
|  | (19.9) | 
 . A meaningful
question is, what is the probability that it has a value in the
interval
. A meaningful
question is, what is the probability that it has a value in the
interval  around the value
 around the value  .
.
Making  an infinitesimal we have,
 an infinitesimal we have,
|  | (19.10) | 
 is probability of getting a value in the internal
 is probability of getting a value in the internal 
 to
 to 
 .  If all values in the range
.  If all values in the range
 to
 to  are equally probable then,
 are equally probable then,
|  | (19.11) | 
 is called the probability density. It  has the
properties:
 is called the probability density. It  has the
properties:
 
 gives the
  probability that
 gives the
  probability that  has a value in the range
 has a value in the range  to
 to  .
.
 Total
  probability is
 Total
  probability is 
We first normalize the probability density. This means to ensure that
 .
Applying this condition we have,
.
Applying this condition we have,
|  |  | ||
|  | ![$\displaystyle \left. \frac{A}{2} \left[ \pi - \frac{1}{2} \sin (2x)\right\vert _0^\pi
\right] = \frac{\pi A}{2} =1,$](img1527.png) | (19.13) | 
|  | (19.14) | 
 . The
sum in equation (19.3) is now replaced by an integral and,
. The
sum in equation (19.3) is now replaced by an integral and,
|  | (19.15) | 
|  | (19.16) | 
|  | (19.17) | 
|  |  |  | |
|  | (19.18) | 
Problem Calculate the variance  for the
probability distribution in equation (19.12).
 for the
probability distribution in equation (19.12).
We now return to the wave   associated with every
particle. The laws governing this wave are referred to as Quantum
Mechanics. We have already learnt that this wave is to be
interpreted as the probability amplitude. The probability
amplitude can be used to calculate the probability density
 associated with every
particle. The laws governing this wave are referred to as Quantum
Mechanics. We have already learnt that this wave is to be
interpreted as the probability amplitude. The probability
amplitude can be used to calculate the probability density
 using,
 using,
|  | (19.19) | 
 
 around the point
 around the point  . The expectation value of
the particle's position can be calculated using,
. The expectation value of
the particle's position can be calculated using,
 
 are measured these values will be centered around
 are measured these values will be centered around
 .  The spread in the measured values of
.  The spread in the measured values of  is
quantified through the variance,
 is
quantified through the variance,
|  | (19.20) | 
The standard deviation which is also denoted as 
 gives an estimate of the
uncertainty in the particle's position.
 gives an estimate of the
uncertainty in the particle's position.
 in seven identical
  replicas of the same system we get values
 in seven identical
  replicas of the same system we get values  ,
,  , ,
, ,
 ,
,  ,
,  and
 and  .  What are the expectation value and
  uncertainty in
.  What are the expectation value and
  uncertainty in  ?
?
 is found to be different each
  time  the experiment is performed. The values of
 is found to be different each
  time  the experiment is performed. The values of  are found to be
  always positive, and the distribution is found to be well described
  by a probability density
 are found to be
  always positive, and the distribution is found to be well described
  by a probability density
![\begin{displaymath}\rho(x)=\frac{1}{L} \exp[-x/L] \hspace{1cm} L=0.2 \, {\rm m}\end{displaymath}](img1548.png) 
 if the experiment is
  performed  once?
 if the experiment is
  performed  once?
 ?
?
 is less than
 is less than 
 ?
?
 are less than
 are less than 
 ?
?
 .
.
 ?
?
 ?
?
 has a positive value?
 has a positive value?
 
 
 
 
 
 
